Potassium Ozonide (KO3): Properties, Structure and Stability

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Potassium Ozonide ($KO_3$): The Ruby-Red, Metastable Mystery of Oxygen Chemistry

When most people think of oxygen compounds, they picture familiar substances like water ($H_2O$), carbon dioxide ($CO_2$), or perhaps simple metal oxides like rust. However, pushing oxygen chemistry to its limits unlocks exotic and highly reactive phases. Among the most striking of these is potassium ozonide ($KO_3$), an inorganic salt defined by its vibrant red-orange color, its unusual magnetic properties, and its inherent instability.


What is Potassium Ozonide?

Potassium ozonide is an ionic compound composed of potassium cations ($K^+$) and ozonide anions ($O_3^-$). Unlike typical oxides or peroxides, the ozonide ion packs three oxygen atoms together with a single negative charge.

  • Chemical Formula: $KO_3$
  • Appearance: Vibrant ruby-red to orange-red crystalline solid
  • Molar Mass: 87.095 g/mol
  • Crystal Structure: Tetragonal lattice system, displaying distinct pleochroism under polarized light

Where It Fits in Oxygen Chemistry

To appreciate $KO_3$, it helps to look at the progression of oxygen anions:

  1. Oxides ($O^{2-}$): Normal oxygen with a -2 oxidation state (

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